MIT engineers developed a way to make clean ammonia, without fossil-fuel-powered chemical plants, using the Earth as a geochemical reactor, producing ammonia underground.
Ammonia is the most widely produced chemical in the world today, used primarily as a source for nitrogen fertilizer. Its production is also a major source of greenhouse gas emissions — the highest in the whole chemical industry. Now, a team of researchers at MIT has developed an innovative way of making ammonia without the usual fossil-fuel-powered chemical plants that require high heat and pressure. Instead, they have found a way to use the Earth itself as a geochemical reactor, producing ammonia underground. The processes uses Earth's naturally occurring heat and pressure, provided free of charge and free of emissions, as well as the reactivity of minerals already present in the ground. The trick the team devised is to inject water underground, into an area of iron-rich subsurface rock. The water carries with it a source of nitrogen and particles of a metal catalyst, allowing the water to react with the iron to generate clean hydrogen, which in turn reacts with the nitrogen to make ammonia. A second well is then used to pump that ammonia up to the surface. The process, which has been demonstrated in the lab but not yet in a natural setting, is described today in the journal Joule. The paper's co-authors are MIT professors of materials science and engineering Iwnetim Abate and Ju Li, graduate student Yifan Gao, and five others at MIT. "When I first produced ammonia from rock in the lab, I was so excited," Gao recalls. "I realized this represented an entirely new and never-reported approach to ammonia synthesis.'" The standard method for making ammonia is called the Haber-Bosch process, which was developed in Germany in the early 20th century to replace natural sources of nitrogen fertilizer such as mined deposits of bat guano, which were becoming depleted. But the Haber-Bosch process is very energy intensive: It requires temperatures of 400 degrees Celsius and pressures of 200 atmospheres, and this means it needs huge installations in order to be efficient.…