Australian scientists say they've made a "eureka moment" breakthrough in gas separation and storage that could radically reduce energy use in the petrochemical industry, while making hydrogen much easier and safer to store and transport in a powder.
Nanotechnology researchers, based at Deakin University's Institute for Frontier Materials, claim to have found a super-efficient way to mechanochemically trap and hold gases in powders, with potentially enormous and wide-ranging industrial implications. Mechanochemistry is a relatively recently coined term, referring to chemical reactions that are triggered by mechanical forces as opposed to heat, light, or electric potential differences. In this case, the mechanical force is supplied by ball milling – a low-energy grinding process in which a cylinder containing steel balls is rotated such that the balls roll up the side, then drop back down again, crushing and rolling over the material inside. The team has demonstrated that grinding certain amounts of certain powders with precise pressure levels of certain gases can trigger a mechanochemical reaction that absorbs the gas into the powder and stores it there, giving you what's essentially a solid-state storage medium that can hold the gases safely at room temperature until they're needed. The gases can be released as required, by heating the powder up to a certain point. Mechanochemical separation of gases using ball milling Deakin University The process is repeatable, and Professor Ian Chen, co-author on the new study published in the journal Materials Today, tells us via phone that the boron nitride powder used in the first experiments only loses "about a couple of percent" of its absorption capability each storage and release cycle. "Boron nitride is very stable," he tells us, "and graphene too. We're looking at a restoration treatment that can clean the powders and restore their absorption levels, but we need to prove that it'll work." A revolutionary overhaul of the massive gas separation industry The results are absolutely remarkable from a numbers standpoint. This process, for example, could separate hydrocarbon gases out from crude oil using less than 10% of the energy that's needed today. "Currently,…